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b. It must not freeze at temperatures above 15 C (5 F). The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. 362 This entry applies to liquids, pastes or powders, pressurized with a propellant that meets the definition of a gas in 173.115. W8 Vessel stowage category for pyrophoric thorium metal or pyrophoric uranium metal is D as defined in 172.101(k)(4). The suitability for transport in tanks must be demonstrated using test 8(d) in Test Series 8 (see UN Manual of Tests and Criteria, Part 1, Sub-section 18.7) (IBR, see 171.7 of this subchapter) or an alternative means approved by the Associate Administrator. For liquids transported under ambient conditions may be calculated using the formula: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. 370 This entry also applies to ammonium nitrate with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any added substance, that gives a positive result when tested in accordance with Test Series 2 of the UN Manual of Tests and Criteria, Part I (IBR; see 171.7 of this subchapter). 172.101 Hazardous Materials Table (HMT). Other inorganic nitrate salts may replace part of the ammonium nitrate. Dry batteries not specifically covered by another entry in the 172.101 Table are covered by this entry (i.e., Batteries, dry, sealed, n.o.s.) This is in response to your November 18, 2015 e-mail and subsequent conversations with members of my staff requesting clarification of the Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to the selection of a . (4) Each detector must be tested to a 1 1010 cm3/s leaktightness standard before filling. IBCs must have a device to allow venting. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. B46 The detachable protective housing for the loading and unloading valves of multi-unit tank car tanks must withstand tank test pressure and must be approved by the Associate Administrator. B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. B14 Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. (a) General. 51 This description applies to items previously described as Toy propellant devices, Class C and includes reloadable kits. TP4 The maximum degree of filling for portable tanks must not exceed 90%. TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. iv. (i) Tests must be performed on each type and size of bottle, for each manufacturing location. Each reference in this column to a material which is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter "A" or "W", is modified to include " 173.203" or " 173.213", as appropriate for liquids and solids, respectively, on those occasions when the . 49 Mixtures of solids that are not subject to this subchapter and corrosive liquids may be transported under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. 345 Nitrogen, refrigerated liquid (cryogenic liquid), UN1977 transported in open cryogenic receptacles with a maximum capacity of 1 L are not subject to the requirements of this subchapter. Columns 8A, 8B and 8C specify the applicable sections for . Each Each transport unit must be leakproof when used as bulk packaging. It may not be used to describe articles, machinery, or apparatus for which a proper shipping name exists in the 172.101 Table. a. TP21 The wall thickness must not be less than 8 mm. With less than 10 percent formaldehyde, are not subject to this subchapter. Shipment of packages under this special provision must be made by private or contract motor carrier. 6 This material is poisonous-by-inhalation and must be described as an inhalation hazard under the provisions of this subchapter. N43 Metal drums are permitted as single packagings only if constructed of nickel or monel. Displaying title 49, up to date as of 3/02/2023. When a specific portable tank instruction is specified by a T Code in Column (7) of the 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if: (A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified); (B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified); (C) The alternative portable tank has a pressure relief device as specified in the T Code. If the SADT of the technically pure substance is higher than 75 C, the technically pure substance and formulations derived from it are not self-reactive materials and, if not meeting any other hazard class, are not subject to the requirements of this subchapter. result, it may not include the most recent changes applied to the CFR. 177 Gasoline, or, ethanol and gasoline mixtures, for use in internal combustion engines (e.g., in automobiles, stationary engines and other engines) must be assigned to Packing Group II regardless of variations in volatility. There you have it! If a tank car tank is equipped with a non-reclosing pressure relief device, the rupture disc must be perforated with a 3.2 mm (0.13 inch) diameter hole. N11 This material is excepted for the specification packaging requirements of this subchapter if the material is packaged in strong, tight non-bulk packaging meeting the requirements of subparts A and B of part 173 of this subchapter. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. Column 7 specifies codes for special provisions applicable to hazardous materials. In addition, MC 312 and DOT 412 cargo tank motor vehicles must: a. B49 Tanks equipped with interior heater coils are not authorized. N83 This material may not be transported in quantities of more than 11.5 kg (25.4 lbs) per package. (contains magnesium, magnesium nitrides) in PG II or III may be packaged in sift-proof bulk packagings that prevent liquid from reaching the hazardous material with sufficient venting to preclude dangerous accumulation of flammable, corrosive or toxic gaseous emissions such as methane, hydrogen and ammonia. "Published Edition". For this test, the provisions of paragraphs 16.6.1.2 except letter g, 16.6.1.3.1 to 16.6.1.3.6, 16.6.1.3.7(b) and 16.6.1.3.8 of the UN Manual of Tests and Criteria must be applied. A30 Ammonium permanganate is not authorized for transportation on aircraft. A82 The quantity limits in columns (9A) and (9B) do not apply to human or animal body parts, whole organs or whole bodies known to contain or suspected of containing an infectious substance. It is shown that it does not pose a significant risk in transportation; b. (7) Special Provisions (172.102) IB8, IP2, IP4 Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. A6 For combination packagings, if plastic inner packagings are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. A54 Irrespective of the quantity limits in Column 9B of the 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment that otherwise meets the applicable requirements of 173.185, may have a mass exceeding 35 kg if approved by the Associate Administrator prior to shipment. 21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see 173.21(f) of this subchapter). A current copy of CGA pamphlet, CGA C-6 must be available at the facility servicing the life-saving appliance. The objects must be secured to the flat car, motor vehicle, intermodal container, or unitized by steel banding to wooden runners or pallets and the units secured to the flat car, motor vehicle, or freight container to prevent shifting, including relative motion between the objects, under conditions normally incident to transportation. Examples of such vehicles are electrically-powered cars, motorcycles, scooters, three- and four-wheeled vehicles or motorcycles, trucks, locomotives, bicycles (pedal cycles with an electric motor) and other vehicles of this type (e.g., self-balancing vehicles or vehicles not equipped with at least one seating position), lawn tractors, self-propelled farming and construction equipment, boats, aircraft, wheelchairs and other mobility aids. This includes hybrid electric vehicles powered by a fuel cell, an internal combustion engine, and wet, sodium or lithium batteries installed. A29 Combination packagings consisting of outer expanded plastic boxes with inner plastic bags are not authorized for transportation by aircraft. b. 347 Effective July 1, 2011, for transportation by aircraft, this entry may only be used if the results of Test series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. Be ASME Code (U) stamped for 100% radiography of all pressure-retaining welds; b. The battery has been tested as a primary lithium battery; and. learn more about the process here. Formaldehyde solutions not containing methanol and not meeting the Class 3 flammable liquid criteria must be described using a different proper shipping name. The purpose of this article is to explain the meaning of the coding system for the Special Provisions of column 7 in order to facilitate your review and understanding of them and how they may apply to your shipment of a hazardous material. The Packing Group assigned will be II or III, according to the classification criteria for either Class 3 or Division 4.1, as appropriate, applied to the base material. A212 UN 2031, Nitric acid, other than red fuming, with more than 20% and less than 65% nitric acid intended for use in sterilization devices only, may be transported on passenger aircraft irrespective of the indication of forbidden in columns (9A) of the 172.101 table provided that: a. The presence of a Class 8 hazard must be communicated as required by this part for subsidiary hazards. d. The proper shipping name Printing ink related material may be used for consignments of packages containing Printing ink and Printing ink related material in the same package. Using the nominal capacitance (CN), rated voltage (UR) and the rated lower limit voltage (UL). not more than 0.1 mL/hour per 30 mL inner packaging at 20 C (68 F) produced from gradual decomposition. Subpart BTable of Hazardous Materials and Special Provisions 172.101 Purpose and use of haz-ardous materials table. Such packages must be transported on cargo aircraft only. For a battery whose voltage (electrical potential) exceeds 9 volts -, (1) When contained in a device, the device must be packaged in a manner that prevents unintentional activation or must have an independent means of preventing unintentional activation (e.g., packaging restricts access to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive circuit breakers, etc. 156 Asbestos that is immersed or fixed in a natural or artificial binder material, such as cement, plastic, asphalt, resins or mineral ore, or contained in manufactured products is not subject to the requirements of this subchapter. 105 The word Agents may be used instead of Explosives when approved by the Associate Administrator. The packaging shall be designed for a working temperature of at least 121 C (250 F). (TOY CAPS) - HANDLE CAREFULLY OR TOY CAPS - HANDLE CAREFULLY; and. 388 a. Lithium batteries containing both primary lithium metal cells and rechargeable lithium ion cells that are not designed to be externally charged, must meet the following conditions: i. Additionally, each cylinder must be visually inspected in accordance with CGA pamphlet, CGA C-6 (incorporated by reference, see 171.7). 61 A chemical oxygen generator is spent if its means of ignition and all or a part of its chemical contents have been expended. B78 Tank cars must have a test pressure of 4.14 Bar (60 psig) or greater and conform to Class 103, 104, 105, 109, 111, 112, 114 or 120. N37 This material may be shipped in an integrally-lined fiber drum (1G) which meets the general packaging requirements of subpart B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the material and to any other special provisions of column 7 of the 172.101 table. View the most recent official publication: These links go to the official, published CFR, which is updated annually. The only tank car tanks authorized are Class DOT 105 tank cars having a test pressure of 2,069 kPa (300 psig) or greater. These provisions apply only to transportation by water: W1 This substance in a non friable prill or granule form is not subject to the requirements of this subchapter when tested in accordance with the UN Manual of Test and Criteria (IBR, see 171.7 of this subchapter) and is found to not meet the definition or criteria for inclusion in Division 5.1. Lead-free Solder Figure 3: Engineer soldering a microcircuit Note, Tin here is the primary metal. PDF Special Provision Letter Codes Used in Hazmat Table, Column 7 Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. The requirements of 173.24(g)(1) and 173.27(c) do not apply. 49 U.S.C. 5 If this material meets the definition for a material poisonous by inhalation (see 171.8 of this subchapter), a shipping name must be selected which identifies the inhalation hazard, in Division 2.3 or Division 6.1, as appropriate. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. The HMT provides the basic information necessary to ship a hazardous material safely. See 173.306(h) of this subchapter. These provisions are multi-modal and apply to bulk and non-bulk packagings: 1 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone A (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Comparative fire testing between a package as prepared for transport (including the substance to be transported) and an identical package filled with water must show that the maximum temperature measured inside the packages during testing does not differ by more than 200 C (392 F).