" I learned many different ways to improve my techniques with current and future customers. Alex Petrovic, Auto-Wares", .ec_product_details_star_off:before{ border-bottom-color:#CCCCCC; } B. " I came in not knowing what to expect and I was blown away. Tano Archuleta, Painter Supply Co.", WebQC is a web application with a mission to provide best-in-class chemistry tools and information to chemists and students. .ec_category_li{ width:100%; } which contains the largest number units" of that stuff. status page at https://status.libretexts.org. .ec_details_images{ width:47%; } What amount (in moles) is present in 2.0 g of sodium hydroxide, NaOH? .ec_product_type6 .ec_image_container_none, .ec_product_type6 .ec_image_container_border, .ec_product_type6 .ec_image_container_shadow{ width:100%; max-width:100%; } .ec_cart_widget_minicart_wrap{ background:#222222; } There are two moles of hydrogen atoms and one mole of oxygen atoms in one mole of water. quotes: [" Very thorough, specific to our needs in a relationship / customer service business. What is the reflection of the story of princess urduja? Clearly, the mole is so large that it is useful only for measuring very small objects, such as atoms. } .ec_details_customer_review_data{ color:#222222; } .ec_details_magbox{ display:none !important } $('#annoyingtags').css('display', 'none');
.ec_product_added_to_cart a:hover, .ec_cart_checkout_link:hover{ color:#666666 !important; } .ec_cart_button_row a.ec_account_login_link:hover{ background:none !important; background-color:transparent !important; color:#666666; } C Add together the masses to give the molecular mass. 5 g of an unknown substance . {color:#424242;}.breadcrumb a:hover .ec_cart_right > .ec_cart_header.ec_top{ margin-top:15px; } .ec_category_li:nth-child( 2n+1 ) .ec_product_editor{ left:227px; } The numerical value of Avogadro's number, usually written as No, is a consequence of the arbitrary value of one kilogram, a block of Pt-Ir metal called the International Prototype Kilogram, and the choice of reference for the atomic mass unit scale, one atom of carbon-12. How many carbon atoms, hydrogen atoms, and lone pairs are in the molecule shown below? If the molar mass of the compound is 132.1 g/mol, what is the molecular formula? First, you need to know the chemical formula for water, which is \(\ce{H_2O}\). D. I, II and III atoms C. 2) Consider samples of phosphine (PH 3), water (H 2 O), hydrogen sulfide (H 2 S), and hydrogen fluoride (HF), each with a mass of 105 g. Rank the compounds from least to the greatest number of hydrogen atoms moles How many grams of Sodium Sulfate (Na 2 SO 4) are present in a sample containing 0.176 moles ? Atoms are so small, however, that even 500 atoms are too small to see or measure by most common techniques. .ec_account_dashboard_row_divider a, .ec_account_order_line_column5 a, .ec_account_complete_payment_button{ background-color:#222222 !important; } .ec_newsletter_content input[type='submit']{ background-color:#222222;} .recent_posts .date, display: inline !important; CHEM TEST #2 Flashcards | Quizlet .ec_details_right{ padding-left:0px; } " [Norm was] well prepared, lively, funny, entertaining. Mike Hoholik", CH 2 Cl 2 is a slightly . In this case, the mole is used as a common unit that can be applied to a ratio as shown below: 2 mol H + 1 mol O = 1 mol H 2 O Among its many uses, ethanol is a fuel for internal combustion engines. The element carbon exists in two primary forms: graphite and diamond. .ec_product_quickview_content_quantity .ec_minus, .ec_product_quickview_content_quantity .ec_plus{ background-color:#222222; } That means there are 9 H for every molecule. This number is referred to as Avogadro's document.getElementById('quoterotator').innerHTML="No Quotes Found"; =2.4088 x 10^24 atoms of H. Advertisement. .ec_newsletter_content input[type='submit']:hover{ background-color:#666666; } .ec_details_right{ padding-left:0px; } #ec_current_media_size{ max-width:989px; } Best presenter I have ever had in the 11 years I have been in the industry. Adam Aricik, Auto-Wares", .ec_out_of_stock_notify_title, .ec_out_of_stock_notify_button > input{ background-color:#222222; } 0.050 C. 20 B. One mole is equal to 6.022 x 1023. If we did not know aboutmolesand just knew about numbers of atoms or molecules (those big numbers that require lots of superscripts), life would be much more complicated and we would make many more typing errors. It will help me be a more efficient Manager and team leader. .ec_cart_right{ width:100%; padding-left:0px; } jQuery(document).ready(function(jQuery){jQuery.datepicker.setDefaults({"closeText":"Close","currentText":"Today","monthNames":["January","February","March","April","May","June","July","August","September","October","November","December"],"monthNamesShort":["Jan","Feb","Mar","Apr","May","Jun","Jul","Aug","Sep","Oct","Nov","Dec"],"nextText":"Next","prevText":"Previous","dayNames":["Sunday","Monday","Tuesday","Wednesday","Thursday","Friday","Saturday"],"dayNamesShort":["Sun","Mon","Tue","Wed","Thu","Fri","Sat"],"dayNamesMin":["S","M","T","W","T","F","S"],"dateFormat":"MM d, yy","firstDay":1,"isRTL":false});}); Ace Combat 7 Mrp Glitch, B The number of moles of ethylene glycol present in 35.00 g can be calculated by dividing the mass (in grams) by the molar mass (in grams per mole): \( \; 35.00\; g\; ethylene glycol\left ( \frac{1\; mol\; ethylene\; glycol\; (g))}{62.068\; g\; ethylene\; glycol} \right )=0.5639\; mol\; ethylene\; glycol\). C Adding together the masses gives the molecular mass: 24.022 amu + 6.0474 amu + 15.9994 amu = 46.069 amu, Alternatively, we could have used unit conversions to reach the result in one step, as described in Essential Skills 2, \( \left [ 2\; atoms\: \; \left ( \dfrac{12.011\; amu}{1\, \; atom\; C} \right ) \right ] +\) \( \left [ 6\; atoms\: H\; \left ( \dfrac{1.0079\; amu}{1\, \; atom\; H} \right ) \right ]+\) \( \left [ 1\; atoms\: O\; \left ( \dfrac{15.9994\; amu}{1\, \; atom\; O} \right ) \right ] \). molar mass and molecular weight. Haunted Woods Wisconsin, Chapter 1.7: The Mole and Molar Mass - Chemistry LibreTexts 1 g of CH2Cl2 His easy-going demeanor and humble technique makes this class very worthy and not intimidating. Greg Rickard, PPG Industries Inc. ", Figure 1.7.2 A Flowchart for Converting between Mass; the Number of Moles; and the Number of Atoms, Molecules, or Formula Units, For 35.00 g of ethylene glycol (HOCH2CH2OH), which is used in inks for ballpoint pens, calculate the number of, Asked for: number of moles and number of molecules. Determine the number of CH 2 Cl 2 molecules in 25.1 g CH 2 Cl 2. common chemical compounds. " Norm is an excellent facilitator. The molecular mass The sum of the average masses of the atoms in one molecule of a substance, each multiplied by its subscript. How many hydrogen atoms are contained in one mole of ethanol, C2H5OH? It will keep me on track and make me plan better. Andrew Yulle", One mole always has the same number of objects: 6.022 1023. around with a buddy as H2 and not as a single atom. How long will the footprints on the moon last? Molar mass of CH2Cl2 is 84.9326 g/mol Compound name is dichloromethane Get control of 2022! We have 2H2 + O2 in 1 mole you have 6.022*10^23 molecules. 1. Suppose there are 602 000 000 000 000 000 000 atoms in one mole of CH2F2 Lewis Structure, Molecular Geometry - Techiescientist B. 10.2: Conversions Between Moles and Atoms - Chemistry LibreTexts border: none !important; Answer to: How many hydrogen atoms are there in 1.35 g of methane (CH_4)? In this case, the periodic table tells us there is 1g of hydrogen per mole. } " The course gives clear vision and a set plan to help attack and capture more business in current accounts and a way to be successful in building a new customer base. David Johnson", [Solved]: A sample of propane, C3H8C3H8, contains 10.3 moles Legal. 6 C. 1.01023 D. 3.61024 D The percentage by mass of the elements in a compound is C = 72%, H = 12%, O = 16%. (a) Name the elements of the intrinsic conduction system of the heart in order, beginning with the pacemaker. A. img.emoji { Verifying Avogadro's Hypothesis Video from HC Communications on YouTube. They called this number Avogadros Number (N A) in honour of Amadeo Avogadro, and the number is 6.02 x 1023 which is equal to one mole of any atoms, ions or molecules. Atoms can be defined as a smallest unit of ordinary matter that forms a chemical elements. http://commons.wikimedia.org/wiki/File:Man_responds_to_telephone_call.jpg(opens in new window), http://commons.wikimedia.org/wiki/File:Water-3D-balls-A.png(opens in new window), source@https://flexbooks.ck12.org/cbook/ck-12-chemistry-flexbook-2.0/, status page at https://status.libretexts.org, number of \(\ce{C}\) atoms \(= 4.72 \times 10^{24}\), \(1\) mole \(= 6.02 \times 10^{23}\) atoms, \(1\) mole \(= 6.02 \times 10^{23}\) molecules \(\ce{H_2SO_4}\). " You can see the passion in Norman\'s work, his belief in his programs makes it easy to follow and the info is delivered in a fun and easy to learn manner. Sunny Grewal", If you have one mole of people, they would How many moles of Iron (Fe) are present in a sample containing 4.41 10 22 atoms? background: none !important; .ec_product_type6 .ec_product_meta_type6 .ec_product_addtocart:hover, .ec_product_meta_type6 .ec_product_addtocart a.ec_added_to_cart_button:hover{ background-color:#666666 !important; } .ec_product_type5 .ec_product_quickview > input:hover{ background:#222222; background-color:#222222; } How many hydrogen atoms are in 5 molecules of isopropyl alcohol, B Taking the atomic masses from the periodic table, we obtain, \( 2 \times atomic;\ mass\;of\:carbon = 2\;atoms \left( {\dfrac{12.011amu}{atom}} \right) = 24.022\;amu\), \( 6 \times atomic;\ mass\;of\:hydrogen = 6\;atoms \left( {\dfrac{1.0079amu}{atom}} \right) = 6.0474\;amu\), \( 1 \times atomic;\ mass\;of\:oxygen = 1\;atoms \left( {\dfrac{15.9994amu}{atom}} \right) = 15.9994amu\). Avogadro's number is the fundamental constant that is least accurately determined. .ec_cart_right{ width:100%; padding-left:0px; } .ec_product_details_star_off:after{ color:#CCCCCC; border-bottom-color:#CCCCCC; } .ec_details_manufacturer{ color:#666666 !important; } Conversely, it enables chemists to calculate the mass of a substance needed to obtain a desired number of atoms, molecules, or formula units. 58 grams . .ec_details_categories{ color:#666666 !important; } #ec_current_media_size{ max-width:1300px; } In the laboratory, for example, the masses of compounds and elements used by chemists typically range from milligrams to grams, while in industry, chemicals are bought and sold in kilograms and tons. What is the mass in grams of 0.42 moles of Al2O3 ? How about in a dozen? The problem for Dalton and other early chemists was to discover the quantitative relationship between the number of atoms in a chemical substance and its mass. = 2H2O because oxygen is diatomic like hydrogen. B The formula mass of Ca(ClO)2 is obtained as follows: The molar mass of Ca(ClO)2 is 142.983 g/mol, \( moles\; Ca\left ( ClO \right )_{2}\left [ \dfrac{molar\; mass\; Ca\left ( ClO \right )_{2}}{1\; mol\; Ca\left ( ClO \right )_{2}} \right ]=mass\; Ca\left ( ClO \right )_{2} \), \( 1.75\; mol\; Ca\left ( ClO \right )_{2}\left [ \dfrac{142.983\; g Ca\left ( ClO \right )_{2}}{1\; mol\; Ca\left ( ClO \right )_{2}} \right ]=250.\; g\; Ca\left ( ClO \right )_{2} \). .ec_category_li:nth-child( 1n+1 ){ clear:both; } " This course not only assists in day to day practices but everyday life. .ec_special_heading{ color:#222222; } This molecule and its molecular formula indicate that per mole of methane there is 1 mole of carbon and 4 moles of hydrogen. Metal Framing Jobs Near Me, .ec_details_mobile_title_area{ display:block; } By using this website, you signify your acceptance of Terms and Conditions and Privacy Policy.Do Not Sell My Personal Information padding: 0 !important; This is not much help in the laboratory for the typical chemist who only has a balance to weight out chemicals but needs to know how the number of atoms or molecules. 0.5 mol NaCl 5 B. .ec_product_li, li.ec_product_li{ width:50%; } B. Using the concept of the mole, we can now restate Daltons theory: 1 mol of a compound is formed by combining elements in amounts whose mole ratios are small whole numbers. Express the total number of moles of carbon and hydrogen numerically. Ace Combat 7 Mrp Glitch, So it is: $$8.66 \cdot 6.02 \cdot 10^{23} = 5.21332 \cdot 10^{24}$$ .ec_category_li:nth-child( 2n+1 ) .ec_product_editor{ left:227px; } a.ec_cart_empty_button{ background-color:#222222 } #ec_cart_payment_one_column{ display:block; } In the following video, Prof. Steve Boon shows how Avogadro's hypothesis can be used to measure the molecular masses of He, N2 and CO2. How many moles of hydrogen atoms are there in one mole of (NH4 - Quora At t=0, an automobile traveling north begins to make a turn. span.price, .ec_details_related_products_area > h3{ color:#222222 !important; } A. B. /*]]>*/. These relative weights computed from the chemical equation are sometimes called equation weights. Because a molecule or a polyatomic ion is an assembly of atoms whose identities are given in its molecular or ionic formula, we can calculate the average atomic mass of any molecule or polyatomic ion from its composition by adding together the masses of the constituent atoms. We also described the law of multiple proportions, which states that the ratios of the masses of elements that form a series of compounds are small whole numbers. .ec_product_type3 .ec_product_addtocart:hover{ background-color:#666666 !important; } .ec_product_type6 .ec_product_meta_type6 .ec_price_container:after{ border-color:#666666 transparent transparent #666666; } .ec_category_li:nth-child( 2n+1 ) .ec_product_editor{ left:227px; } How many moles of calcium hydroxide are made from 5.3 moles of water? One mole of carbon still has 6.022 1023 carbon atoms, but 98.89% of those atoms are carbon-12, 1.11% are carbon-13, and a trace (about 1 atom in 1012) are carbon-14. Hydrogen atom - Wikipedia #navigation_bar > ul > li > a {font-family:"Droid Sans";}#footer {background-color: rgba(255,255,255, 0.3);} The Configuration of the Water Molecule | EARTH 111: Water: Science and .rss-date, According to the most recent experimental measurements, this mass of carbon-12 contains 6.022142 1023 atoms, but for most purposes 6.022 1023 provides an adequate number of significant figures. } .ec_category_li:nth-child( 2n+1 ){ clear:both; } The mass number is an integer that is approximately equal to the numerical value of the atomic mass. How Did James Hunt Die, If not, there are 2mol Carbon for every mol of C2H5OH. __ CH3CHO + __ O2 __ CO2 + __ H2O One mole of H 2 O is 6.022 x 10 23 molecules of H 2 O ( Avogadro's number). Haunted Woods Wisconsin, It should be noted that not all . .wpb_animate_when_almost_visible { opacity: 1; }. Methods are described for conversions between moles, atoms, and molecules. The formula weight is simply the weight in atomic mass units of all the atoms in a given formula. The H2 in H2O is not 2 hydrogens bonded to one another and then to oxygen, but two separate hydrogen atoms, each bonded an oxygen atom. It is called the Avogadro Constant, denoted by L and is equal to 6.0210^23 correct to 2 decimal places. What is the final volume of the gas? 6 hydrogen atoms are contained in one mole of ethanol. " I can see where this can be adapted to all areas of life. Dave Houthofz", .ec_product_li:nth-child( 1n+1 ) .ec_product_editor{ left:227px; } margin: 0 .07em !important; When we talk about CH2Cl2, Carbon is less electronegative than Chlorine atoms. " A great guide to sales but also a great guide to how to live your life. The steric number of the carbon central atom in the CH 2 Cl 2 molecule is 4, thus, it forms Sp 3 hybridization. That means that there would be 9 mol of H atoms in 1 mol of (NH4)2HPO4. The expression 2H 2 represents two molecules of diatomic hydrogen ( Figure 2.18 ). " Great class. C. 2 mol of H2O2 What is the mole ratio of C:H in the empirical formula of this compound? blockquote.testimonial p span.author .ec_details_customer_reviews_form > .ec_details_customer_reviews_form_holder > h3{ color:#222222 !important; } It allows determination of the number of molecules or atoms by weighing them. Although the mass number is unitless, it is assigned units called atomic mass units (amu). " Very worthwhile. .ec_cart_button_row a.ec_account_login_link{ background:none !important; background-color:transparent !important; color:#222222; } .ec_product_type1 .ec_product_addtocart:hover{ background-color:#666666; border-bottom-color:#222222; } height: 1em !important; For every mole, there are 6.02*10 23 atoms, so in 1 gram of hydrogen there are 6.02*10 23 hydrogen atoms (in scientific notation . Avogadro's number.) .ec_cartitem_quantity_table > tbody > tr > td > .ec_minus, .ec_cartitem_quantity_table > tbody > tr > td > .ec_plus, .ec_cartitem_quantity_table > tbody > tr > td > .ec_cartitem_update_button{ background-color:#222222 !important; } To calculate the molecular mass of a covalent compound. Therapy Dog Test, CH2F2 or difluoromethane or difluoromethylene is an organic compound of the haloalkane family. .ec_product_type6 .ec_product_meta_type6 .ec_product_addtocart{ background-color:#222222 !important; } How many atoms of hydrogen are in two water molecules? .ec_product_details_page a:hover{ color:#666666; } My friend tells me to multiply the number of atoms by6.02 10. __C2H2(g) + __O2(g) __ CO2(g) + __ H2O(g), 3.0 dm3 of sulfur dioxide is reacted with 2.0 dm3 of oxygen according to the equation, What will happen to the volume of a fixed mass of gas when its pressure and temperature. .ec_quickview_view_details a:hover{ color:#666666 !important; } C. 100 cm3 of 1.0 mol dm-3 NaOH A The molecular formula of ethanol may be written in three different ways: CH3CH2OH (which illustrates the presence of an ethyl group, CH3CH2, and an OH group), C2H5OH, and C2H6O; all show that ethanol has two carbon atoms, six hydrogen atoms, and one oxygen atom. hydrogen which will be 6.022 x 1023 molecules of hydrogen which .ec_cart_input_row > a, .ec_cart_input_row > b, .ec_cart_input_row > strong, .ec_account_order_details_item_display_title > a{ color:#222222; } setInterval('quoteRotator.quoteRotate()', (this.fadeDuration + this.fadeoutDuration + this.delay) * 1000); The mole concept, which we will introduce here, bridges that gap by relating the mass of a single atom or molecule in amu to the mass of a collection of a large number of such molecules in grams. The sum of the average masses of the atoms in one molecule of a substance, each multiplied by its subscript. .ec_category_li{ width:100%; } #ec_current_media_size{ max-width:1139px; } The molar mass of ethanol is the mass of ethanol (C2H5OH) that contains 6.022 1023 ethanol molecules. Briefly explain why each of the following statement is false, or reword it to make it true. The percentage by mass of the elements in a compound is, What amount of NaCl (in moles) is required to prepare 250 cm3 of a 0.200 mol dm-3 Recall that two hydrogen atoms bind to make a hydrogen molecule. I thought it was great and was very informative funny as hell at times also! David Key", " Normans approach was fresh, comfortable and confidence-building. Jacquie Thompson, TD", } else { It makes a difference. Jayson Tuma, Automotive Paint Specialties", .tags a, See Answer Question: 1. " Norm is high energy and keeps you involved. Scott A. Clark, API Inc", CH2Cl2 molecular weight Molar mass of CH2Cl2 = 84.93258 g/mol This compound is also known as Methylene Chloride or Dichloromethane. The first conversion factor converts from moles of particles to the number of particles. (, Which sample has the least number of atoms? Multiply and round the answer to 5 significant figures. (, Which solution contains the greatest amount (in mol) of solute? A mole of oxygen atoms 16 grams while a mole of oxygen molecules is 32 grams. var wpeasycart_ajax_object = {"ajax_url":"https:\/\/www.excelsalesconsulting.com\/wp-admin\/admin-ajax.php","current_language":"EN"}; For example, the equation above would be read as: 1 mole of propane (CH 3 CH 2 CH 3) reacts with 5 moles of oxygen (O 2) to produce 3 moles of carbon dioxide (CO 2) and 4 moles of water (H 2 O) and heat is released. Taco 218 Repair, quotesInit: function(){ .ec_image_container_none, .ec_image_container_none > div, .ec_image_container_border, .ec_image_container_border > div, .ec_image_container_shadow, .ec_image_container_shadow > div{ min-height:310px; height:310px; } Which has the greatest number of hydrogen atoms? (, Which solution contains 0.1 mol of sodium hydroxide? How many atoms of hydrogen are in 1.0 mole of cyanocobalamin. How many hydrogen atoms are there in one mole of CH2Cl2? This relation is then used to 'convert' a number of H 2 O molecules to grams by the ratio: mass of X molecules of H 2 O / X molecules = mass of a mole of H 2 O molecules / 6.022 x 10 23 molecules. .ec_product_type6 .ec_product_meta_type6 .ec_product_addtocart_container{ float:none; } A hydrogen atom is an atom of the chemical element hydrogen.The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Molecular weight of CH2Cl2 - Convert Units 4.8x10^24. Answers: 2 on a question: 1. The original number of oxygen atoms was about 80 times larger than Avogadro's number. C63H88CoN14O14P. .template_builder .sub_title{ Use Avogadro's Number to Convert Molecules to Grams - ThoughtCo Now the mass of hydrogen = 1 gram mass of chlorine = 35.5 grams Therefore, molar mass of CH2Cl2 = 12 + 2 (1) + 2 (35.5) = 85 grams number of moles = mass / molar mass number of moles of CH2Cl2 = 66.05 / 85 = 0.777 moles One mole of CH2Cl2 contains two moles of Cl and each chlorine mole has Avogadro's number of atoms in it. D. 4.0 dm3, The reaction of ethanal and oxygen can be represented by the unbalanced equation below. To avoid toomuch space, write your answer in scientific notation. hydrogen atoms per formula unit, so Avogadro times 88 = about .ec_product_li, li.ec_product_li{ width:100%; } How many moles of sulfuric acid is the sample? Which formulas are possible for this .ec_details_tab.ec_active{ border-top-color:#222222; } .ec_category_li{ width:50%; } .ec_cartitem_quantity_table > tbody > tr > td > .ec_minus:hover, .ec_cartitem_quantity_table > tbody > tr > td > .ec_plus:hover, .ec_cartitem_quantity_table > tbody > tr > td > .ec_cartitem_update_button:hover{ background-color:#666666 !important; } {"@context":"https://schema.org","@graph":[{"@type":"Organization","@id":"https://www.excelsalesconsulting.com/#organization","url":"https://www.excelsalesconsulting.com/","name":"Excel Sales Consulting","sameAs":[]},{"@type":"WebSite","@id":"https://www.excelsalesconsulting.com/#website","url":"https://www.excelsalesconsulting.com/","name":"Excel Sales Consulting","publisher":{"@id":"https://www.excelsalesconsulting.com/#organization"}},{"@type":"WebPage","@id":"https://www.excelsalesconsulting.com/a35pwqle/#webpage","url":"https://www.excelsalesconsulting.com/a35pwqle/","inLanguage":"en-US","name":"how many hydrogen atoms are in one mole of ch2cl2","isPartOf":{"@id":"https://www.excelsalesconsulting.com/#website"},"datePublished":"2021-02-16T02:40:53+00:00","dateModified":"2021-02-16T02:40:53+00:00"},{"@type":"Article","@id":"https://www.excelsalesconsulting.com/a35pwqle/#article","isPartOf":{"@id":"https://www.excelsalesconsulting.com/a35pwqle/#webpage"},"author":{"@id":"https://www.excelsalesconsulting.com/author/#author"},"headline":"how many hydrogen atoms are in one mole of ch2cl2","datePublished":"2021-02-16T02:40:53+00:00","dateModified":"2021-02-16T02:40:53+00:00","commentCount":0,"mainEntityOfPage":{"@id":"https://www.excelsalesconsulting.com/a35pwqle/#webpage"},"publisher":{"@id":"https://www.excelsalesconsulting.com/#organization"},"articleSection":"Uncategorized"},{"@type":"Person","@id":"#person","name":"admin","sameAs":[],"image":{"@type":"ImageObject","@id":"https://www.excelsalesconsulting.com/#personlogo","url":"https://secure.gravatar.com/avatar/99815111078f0ee26a87fd081bb6b614?s=96&d=mm&r=g","width":96,"height":96,"caption":"admin"}}]}